Dear Subordinate,
I can no longer contain myself. I must let you know that I feel your same day request for me to write you a letter of recommendation is quite unacceptable. I would propose that you consider asking me at least a week in advance in the future. If you do not, I will be required to dispense an unintended undesirable notification of investigatory conference or a voodoo curse. All this may come as news to you; however, for what it is worth, lack of planning on your part does not constitute an emergency on my part. I implore you to a) not take this personally, b) let us never speak of this again, and c) seek help from another colleague.
Sincerely,
Your Stabby Supervisor
Throw her a mad libs, fill in the blank letter. That should fix her.